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Science lesson plan · 10th grade (Year 11 in England) · 60 minutes

Predict how an equilibrium shifts (Le Chatelier)

Chemical reactions, acids and bases

CCSS NGSS.HS-PS1-6England: GCSE Combined Science: The rate and extent of chemical change (Higher)

Objective and success criteria

Students will: Predict how an equilibrium shifts (Le Chatelier).

  • I can answer questions on today's skill on my own, without help.
  • I can explain each step and say why it works.
  • I can check my answer and spot a mistake.

Before and after

Needs first: Reaction profiles: energy change and activation energy; Rates of reaction

Leads to: the next skill in this area.

Materials: Teacher demo or video, Indicator color chart, Mini whiteboards, A diagram or short video clip of the idea, Printed student sheet (below).

Warm-up · 6 min

  • Quick retrieval from earlier learning (Reaction profiles: energy change and activation energy; Rates of reaction). Students answer on mini whiteboards.
  • Show answers together and note who needs support in the main task.
  1. On a reaction profile, the reactants are at 80 kJ, the peak is at 140 kJ and the products are at 40 kJ. What is the overall energy change, in kJ? (Use a minus sign if energy is released.) → -40 kJPrompt: energy change = energy of products − energy of reactants
  2. A reaction produces 60 cm³ of gas in 30 seconds. What is the mean rate of reaction, in cm³/s? → 2 cm³/sPrompt: mean rate = amount of product ÷ time
  3. Reactants: 40 kJ. Peak of the profile: 190 kJ. Products: -10 kJ. What is the activation energy, in kJ? → 150 kJPrompt: Activation energy is the minimum energy needed to start the reaction.

Hook · 6 min

  • Drop an antacid tablet in water (or show a clip) and ask whether a new substance is being made.
  • Share the objective: Predict how an equilibrium shifts (Le Chatelier). Read the success criteria together.

I do: model it · 12 min

  • Work through the example out loud, saying why you do each step, not just what you do.
  • Example: All substances are gases in this equilibrium: Nâ‚‚Oâ‚„ ⇌ 2NOâ‚‚. The forward reaction is endothermic. The pressure is increased. What happens to the position of equilibrium?
  • Step 1: Higher pressure favours the side with fewer gas molecules.
  • Step 2: So the answer is: shifts left (more reactants)
  • Answer: shifts left (more reactants)
  • Pause after each step and ask a student to say what comes next.

We do: guided practice · 12 min

  • Do these together. Students try each step on whiteboards before you reveal it.
  • Use the hints as prompts rather than giving the answer.
  1. All substances are gases in this equilibrium: N₂ + 3H₂ ⇌ 2NH₃. The forward reaction is exothermic. The temperature is decreased. What happens to the position of equilibrium? (shifts right (more products) / shifts left (more reactants) / no change in position) → shifts right (more products)Prompt: The system shifts to oppose the change.
  2. What is true at dynamic equilibrium? (Only the forward reaction happens / The forward and reverse reactions happen at the same rate / There are equal amounts of reactants and products / Both reactions have stopped) → The forward and reverse reactions happen at the same ratePrompt: "Dynamic" means still moving.

You do: independent practice · 17 min

  • Students work on the student sheet. Circulate and check the first two answers of every student early.
  • Students who finish: write a question of their own for a partner, with the answer.

The 8 questions are on the student sheet below, with answers in the key.

Exit ticket · 7 min

  • Two questions on their own. Sort answers into got it / nearly / not yet to plan the next lesson.
  1. What effect does a catalyst have on the position of equilibrium? (it shifts it left / none: it only helps equilibrium be reached faster / it shifts it right / it stops the reverse reaction) → none: it only helps equilibrium be reached fasterPrompt: A catalyst speeds up both directions equally.
  2. Equilibrium: which statement is NOT true? (In the Haber process, increasing pressure increases the yield of ammonia. / If a reversible reaction is exothermic in one direction, it is endothermic in the other. / A catalyst increases the yield at equilibrium. / Equilibrium can only be reached in a closed system.) → A catalyst increases the yield at equilibrium.Prompt: Are the amounts equal or just unchanging?

Watch out for

  • Everyday meanings of words getting in the way of the science meaning: define key words explicitly.
  • Remembering facts without the reason: ask "why?" and "what is the evidence?"

Support and stretch

Support

  • Review first: Reaction profiles: energy change and activation energy.
  • Use concrete materials: teacher demo or video.
  • Give the first step of each question, or a partly worked example to finish.
  • Pair with a confident partner for the guided practice.

Stretch

  • Explain a common mistake in writing and how to fix it.
  • Write a word problem that uses today's skill, then solve a partner's.

Homework and more practice

Free online practice with hints and printable worksheets for this skill: eurekami.com/science/grade-10.

Free lesson plan from eurekami.com/lesson-plan-builder

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Predict how an equilibrium shifts (Le Chatelier)

Name

Date

Score/ 8

  1. Question 1

    Equilibrium: which statement is NOT true?

    • A. Reactions stop at equilibrium.
    • B. In the Haber process, increasing pressure increases the yield of ammonia.
    • C. If a reversible reaction is exothermic in one direction, it is endothermic in the other.
    • D. Changing the conditions can change the position of equilibrium.
  2. Question 2

    All substances are gases in this equilibrium: 2SO₂ + O₂ ⇌ 2SO₃. The forward reaction is exothermic. Product is removed as it forms. What happens to the position of equilibrium?

    • A. shifts right (more products)
    • B. shifts left (more reactants)
    • C. no change in position
  3. Question 3

    What effect does a catalyst have on the position of equilibrium?

    • A. it stops the reverse reaction
    • B. none: it only helps equilibrium be reached faster
    • C. it shifts it left
    • D. it shifts it right
  4. Question 4

    All substances are gases in this equilibrium: N₂ + 3H₂ ⇌ 2NH₃. The forward reaction is exothermic. The pressure is decreased. What happens to the position of equilibrium?

    • A. shifts right (more products)
    • B. shifts left (more reactants)
    • C. no change in position
  5. Question 5

    All substances are gases in this equilibrium: N₂O₄ ⇌ 2NO₂. The forward reaction is endothermic. Product is removed as it forms. What happens to the position of equilibrium?

    • A. shifts right (more products)
    • B. shifts left (more reactants)
    • C. no change in position
  6. Question 6

    Heating blue hydrated copper sulfate makes white anhydrous copper sulfate and water. Adding water turns it blue again. What does this show?

    • A. Water is a catalyst
    • B. Copper sulfate is an element
    • C. It is a reversible reaction
    • D. It is a physical change only
  7. Question 7

    All substances are gases in this equilibrium: N₂ + 3H₂ ⇌ 2NH₃. The forward reaction is exothermic. The temperature is increased. What happens to the position of equilibrium?

    • A. shifts right (more products)
    • B. shifts left (more reactants)
    • C. no change in position
  8. Question 8

    All substances are gases in this equilibrium: CO + 2H₂ ⇌ CH₃OH. The forward reaction is exothermic. The pressure is decreased. What happens to the position of equilibrium?

    • A. shifts right (more products)
    • B. shifts left (more reactants)
    • C. no change in position

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Answer key: Predict how an equilibrium shifts (Le Chatelier)

  1. 1. A. Reactions stop at equilibrium.

  2. 2. A. shifts right (more products)

  3. 3. B. none: it only helps equilibrium be reached faster

  4. 4. B. shifts left (more reactants)

  5. 5. A. shifts right (more products)

  6. 6. C. It is a reversible reaction

  7. 7. B. shifts left (more reactants)

  8. 8. B. shifts left (more reactants)